Spanish painter. He was born into an aristocratic family and was educated for a military career. However, he turned to letters and painting at an early age, and in 1660 he was one of the artists who, with
Murillo, founded the Academia de Pintura in Seville. In 1661 he joined the Jerusalem Order of the Knights of Malta and travelled to Malta, where he underwent religious and military training. There he met the Italian painter Mattia
Preti, who was also a member of the Order; the two became friends and established a working relationship. From 1664 on Nñez de Villavicencio travelled to Italy and Spain in the service of the Order and on several occasions was able to return to Seville. He must also have passed through Madrid, as he is known to have been in contact with Charles II.
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